It's not something you can do right from Plesk currently. You could set up the aliased domain as a Frame Forward, but that's not true aliasing.
Via command line one thing you can do is to drop a ServerAlias into the vhost.conf of the domain you want everything to point to. In this example "maindomain.com" is the domain the pages will be served from. "domaintwo.com" is the domain you want to point (alias) to another location.
1. Log in via SSH and -su to root
2. Create a vhost.conf file for the main domain.
cd /home/httpd/vhosts/maindomain.com/conf
nano -w vhost.conf
3. Add a couple of ServerAlias lines.
ServerAlias domaintwo.com
ServerAlias www.domaintwo.com
4. CTRL+X to exit and save the changes.
5. Rebuild websrvmng to get the changes noticed.
/usr/local/psa/admin/sbin/websrvmng -v -a
6. You're done.
Note that the above will
not cause mail sent to domaintwo.com to be delivered to maindomain.com. If you want to make it a complete alias, you'll want to do something like is outlined in
this post.