Ok, I'm assuming u mean to have users be prompted to open/save a .pls file as opposed to it showing up in apache? I never thought it was necessary to edit mime.types for this, but, anyways:
Edit /etc/mime.types and /usr/local/psa/apache/conf/mime.types (I don't know which one Plesk checks)
and add
text/pls
pls
where is you hitting the tab key
(1 tab is enough, but this way it looks cleaner)